{"id":2620,"date":"2025-12-29T13:33:35","date_gmt":"2025-12-29T18:33:35","guid":{"rendered":"https:\/\/sites.williams.edu\/makerspace\/?p=2620"},"modified":"2026-04-13T11:21:57","modified_gmt":"2026-04-13T15:21:57","slug":"rust-patina-and-star-wars-playing-with-copper-infused-pla","status":"publish","type":"post","link":"https:\/\/sites.williams.edu\/makerspace\/projects\/rust-patina-and-star-wars-playing-with-copper-infused-pla\/","title":{"rendered":"Rust, Patina, and Star Wars: Playing with Copper-Infused PLA"},"content":{"rendered":"<div id=\"attachment_2622\" style=\"width: 285px\" class=\"wp-caption alignright\"><a href=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-scaled.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-2622\" class=\"wp-image-2622\" src=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-226x300.jpg\" alt=\"A photo of the copper infused PLA printed Benchy before the oxidization process.\" width=\"275\" height=\"365\" srcset=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-226x300.jpg 226w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-771x1024.jpg 771w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-768x1020.jpg 768w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-1157x1536.jpg 1157w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-1542x2048.jpg 1542w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-before-oxidizing-PXL_20250524_190239930.PORTRAIT.ORIGINAL-scaled.jpg 1928w\" sizes=\"auto, (max-width: 275px) 100vw, 275px\" \/><\/a><p id=\"caption-attachment-2622\" class=\"wp-caption-text\">A photo of the copper infused PLA printed Benchy before the oxidization process.<\/p><\/div>\n<p><span style=\"font-weight: 400\">What if your 3D prints could age like ancient artifacts? That was the question I asked myself when I got my hands on a spool of copper-infused PLA. Unlike ordinary plastic filaments, this one behaves a little more like metal: it shines, it scratches differently, and, best of all, it rusts.<\/span><\/p>\n<p><span style=\"font-weight: 400\">With a little kitchen chemistry (just vinegar and table salt), I discovered that you can accelerate corrosion and grow that gorgeous blue-green patina we usually see on old copper roofs or statues. Suddenly, a simple 3D Benchy boat looked like it had been dredged up from a shipwreck\u2026 or stolen from a galaxy far, far away.<\/span><\/p>\n<h2>The Secret Weapon: A New Nozzle<\/h2>\n<div id=\"attachment_2623\" style=\"width: 285px\" class=\"wp-caption alignright\"><a href=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-scaled.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-2623\" class=\"wp-image-2623\" src=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-226x300.jpg\" alt=\"During the submersion, the copper failed to oxidize in the vinegar and salt solution because there was no oxygen available. \" width=\"275\" height=\"365\" srcset=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-226x300.jpg 226w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-771x1024.jpg 771w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-768x1020.jpg 768w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-1157x1536.jpg 1157w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-1542x2048.jpg 1542w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Copper-PLA-failed-oxidizing-PXL_20250525_032513317.PORTRAIT-scaled.jpg 1928w\" sizes=\"auto, (max-width: 275px) 100vw, 275px\" \/><\/a><p id=\"caption-attachment-2623\" class=\"wp-caption-text\">During the submersion, the copper failed to oxidize in the vinegar and salt solution because there was no oxygen available.<\/p><\/div>\n<p><span style=\"font-weight: 400\">B<\/span><span style=\"font-weight: 400\">efore the fun part (corroding things), there\u2019s the practical problem: copper filament is brutal on regular brass nozzles. They get chewed up fast, and I didn\u2019t want to spend my weekends endlessly recalibrating.<\/span><\/p>\n<p><span style=\"font-weight: 400\">So, I splurged on an <\/span><a href=\"https:\/\/e3d-online.com\/products\/e3d-v6-hardened-steel-nozzle?variant=41626547486779\"><span style=\"font-weight: 400\">E3D V6 1.75mm Nozzle<\/span><\/a><span style=\"font-weight: 400\">, a hardened steel nozzle disguised as brass in its heat performance. At $21, it wasn\u2019t exactly cheap, but it meant I could use a variety of filaments, including abrasive ones, without damaging the nozzle. So I can still print fast, but will have less maintenance.&nbsp; In other words, more time experimenting, less time swearing at the printer.<\/span><\/p>\n<h2>Painting with Chemistry<\/h2>\n<div id=\"attachment_2624\" style=\"width: 311px\" class=\"wp-caption alignright\"><a href=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-scaled.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-2624\" class=\"wp-image-2624\" src=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-226x300.jpg\" alt=\"The 3D Benchy boat after (correctly) using a spray bottle (vinegar, water, salt) to initiate the oxidization process.\" width=\"301\" height=\"400\" srcset=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-226x300.jpg 226w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-771x1024.jpg 771w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-768x1020.jpg 768w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-1157x1536.jpg 1157w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-1542x2048.jpg 1542w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/Oxidized-Benchy-Natural-Lighting-No-Filters-PXL_20250822_155137577.PORTRAIT.ORIGINAL-scaled.jpg 1928w\" sizes=\"auto, (max-width: 301px) 100vw, 301px\" \/><\/a><p id=\"caption-attachment-2624\" class=\"wp-caption-text\">The 3D Benchy boat after (correctly) using a spray bottle (vinegar, water, salt) to initiate the oxidization process.<\/p><\/div>\n<p><span style=\"font-weight: 400\">I started with the classic test print: a 3DBenchy boat.<\/span><\/p>\n<p><span style=\"font-weight: 400\">I mixed up my \u201cmagic potion\u201d, vinegar plus salt until it wouldn\u2019t dissolve anymore. I submerged the boat in the <\/span><span style=\"font-weight: 400\">solution and left it for two days and\u2026 nothing happened. I realized that oxidation requires air. So I set it on a tray and sprayed the boat every couple of hours with a cheap misting bottle. A bit of oxidation occurred but it was underwhelming. I experimented and used 220 grit sandpaper to smooth some edges and surfaces of the benchy. I gave it the same corrosion treatment, and waited. Within hours, tiny blue crystals nucleated across its surface like frost on glass. My theory is that sanding exposed more of the copper embedded in the PLA material. Now, each cost of spray deepened the effect and dried differently depending on where the misted liquid pooled, dripped, or got caught on overhangs.<\/span><\/p>\n<p><span style=\"font-weight: 400\">Slowly, the hull blossomed with patches of turquoise and jade crystals. After four days of experimenting, flipping, spraying, and waiting, I finally had my masterpiece: a lost, sunken ship.&nbsp; The edges shimmered like oxidized jewelry, while the lip of the hull turned into a miniature science experiment in evaporation. It felt like I was less \u201cfinishing a print\u201d and more \u201ccollaborating with chemistry.\u201d<\/span><\/p>\n<p><span style=\"font-weight: 400\">It looked ancient, precious, and heavy with story. The corrosion process didn\u2019t just coat the print,&nbsp; it transformed it into something that felt alive, growing, and shifting with each spray. Under natural light, the patina was subtle; under LEDs, it glowed like a relic.<\/span><\/p>\n<p><span style=\"font-weight: 400\">Who knew that a bit of vinegar, salt, and patience could turn plastic into treasure?<\/span><\/p>\n<h2>Final Thoughts<\/h2>\n<div id=\"attachment_2621\" style=\"width: 285px\" class=\"wp-caption alignright\"><a href=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-scaled.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-2621\" class=\"wp-image-2621\" src=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-225x300.jpg\" alt=\"The final look of the 3D Benchy boat after the oxidization process on the copper PLA print.\" width=\"275\" height=\"367\" srcset=\"https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-225x300.jpg 225w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-768x1024.jpg 768w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-1152x1536.jpg 1152w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-1536x2048.jpg 1536w, https:\/\/sites.williams.edu\/makerspace\/files\/2025\/12\/blue-LED-lighting-benchy-copper-oxidation-Wms-MKSP-scaled.jpg 1920w\" sizes=\"auto, (max-width: 275px) 100vw, 275px\" \/><\/a><p id=\"caption-attachment-2621\" class=\"wp-caption-text\">The final look of the 3D Benchy boat after the oxidization process on the copper PLA print.<\/p><\/div>\n<p><span style=\"font-weight: 400\">This project reminded me why I love tinkering: sometimes it\u2019s not about controlling every detail, but about letting the materials surprise you. Copper PLA, a new nozzle, and some kitchen chemistry turned my prints into artifacts that could belong in a museum. And what\u2019s really exciting about this test is that it is another tool the Makerspace has for projects with faculty or students.<\/span><\/p>\n<p><span style=\"font-weight: 400\">And honestly? I\u2019ll never look at table salt the same way again.<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>What if your 3D prints could age like ancient artifacts? That was the question I asked myself when I got my hands on a spool of copper-infused PLA. Unlike ordinary plastic filaments, this one behaves a little more like metal: &hellip; <a href=\"https:\/\/sites.williams.edu\/makerspace\/projects\/rust-patina-and-star-wars-playing-with-copper-infused-pla\/\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":1502,"featured_media":2624,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"ngg_post_thumbnail":0,"footnotes":"","_links_to":"","_links_to_target":""},"categories":[23],"tags":[50,90,104,69,91,103],"class_list":["post-2620","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-projects","tag-3d-printing","tag-copper","tag-experiment","tag-makerspace","tag-oxidization","tag-ship"],"acf":[],"_links":{"self":[{"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/posts\/2620","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/users\/1502"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/comments?post=2620"}],"version-history":[{"count":28,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/posts\/2620\/revisions"}],"predecessor-version":[{"id":3004,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/posts\/2620\/revisions\/3004"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/media\/2624"}],"wp:attachment":[{"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/media?parent=2620"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/categories?post=2620"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/sites.williams.edu\/makerspace\/wp-json\/wp\/v2\/tags?post=2620"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}